国际中文开源期刊平台

有机磷/有机硅/AMPS共聚改性丙烯酸酯乳液的制备及性能研究

Preparation and Properties of Organophosphorus/ silicone /AMPS Copolymerized Acrylate Emulsion

环境与资源 / 2024,6(4)：129-138 / 2025-03-07 28 22

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• 作者： 秦雯霞      黄国俸      李美琦      程浩蓝      陈磊      易超      周林迅      董怡辰     
• 单位：

  重庆科技大学化学化工学院，重庆

• 关键词： 聚丙烯酸酯乳液；有机硅；AMPS；PM-2
• Polyacrylate emulsion; Silicone; AMPS; PM-2
• 摘要： 为了提高丙烯酸酯乳液胶膜的阻燃性能、耐盐离子、耐水性和耐有机溶剂性能，本论文以2-羟乙基甲基丙烯酸酯磷酸酯（PM-2）、乙烯基三乙氧基硅烷、2-丙烯酰胺-2-甲基丙磺酸（AMPS）作为改性剂，制备了改性丙烯酸酯乳液，实验结果表明，当丙烯酸丁酯（BA）与甲基丙烯酸甲酯（MMA）的配比为46%∶54%时，乳胶膜成膜性能良好，胶膜柔韧性适中，外观呈乳白色；当乳化剂的使用量为6%，KPS的用量为1.5%，乙氧基硅烷的用量为4%，AMPS的用量为1%，PM-2的用量为4%时，制备的改性聚丙烯酸酯乳液稳定性良好，储存稳定性和耐钙离子稳定性优异。乳胶膜耐有机溶剂性从被有机溶剂溶解提升到吸油率达到196.53%，拉伸强度达7.12MPa和断裂伸长率可到450%。由此可见，改性能提高乳液的稳定性、乳胶膜的耐水性、耐有机溶剂性和力学强度有显著改善。本研究为聚丙烯酸酯乳液进一步改性研究与应用提供了参考。
• In order to improve the flame retardancy, salt resistance, water resistance and organic solvent resistance of acrylate latex film, modified acrylate emulsion was prepared by using 2- hydroxyethyl methacrylate phosphate (PM- 2), vinyl triethoxy silane, 2- acrylamide -2- methyl propane sulfonic acid (AMPS) as modifier. When the ratio of butyl acrylate (BA) to methyl methacrylate (MMA) is 46%: 54%, the latex film has good film-forming performance, moderate flexibility and milky white appearance; When the amount of emulsifier was 6%, the dosage of KPS was 1.5%, the amount of ethoxy silane was 4%, the dosage of AMPS was 1%, and the amount of PM-2 was 5%, the emulsion had good stability, excellent storage stability and calcium tolerance. the prepared modified PDDA emulsion had good stability, storage stability and calcium ion resistance stability. The organic solvent resistance of the latex film improved from being dissolved in an organic solvent to having an oil absorption rate of 196.53 %. The tensile strength was 7.12 MPa after modification. Elongation at break can reach 450%. It can be seen that the stability of the comprehensive modified emulsion, the water resistance, organic solvent resistance, mechanical strength and flame retardancy of the latex film are significantly improved. This study provides a reference for further modification research and application of polyacrylate.
• DOI： https://doi.org/10.35534/er.0604012
• 引用： 秦雯霞，黄国俸，李美琦，等．有机磷/有机硅/AMPS共聚改性丙烯酸酯乳液的制备及性能研究［J］．环境与资源，2024，6（4）：129-138．